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Structure of the atom and nucleus, isotopes, natural radioactivity and the properties of alpha, beta and gamma radiation, half-life, nuclear reactions, mass energy equivalence, fission and fusion, uses of radioisotopes and radiation hazards.
An atom has a small, dense, positively charged nucleus at the centre with electrons moving around it. The nucleus contains protons (positive) and neutrons (no charge), together called nucleons. The atom is neutral because the number of electrons equals the number of protons. Almost all the mass of the atom is in the nucleus, which is about 100 000 times smaller in size than the atom. Rutherford's alpha particle scattering experiment led to this model: most alpha particles passed through a thin gold foil, a few were deflected strongly and very few bounced back.
Nuclear notation:
Isotopes are atoms of the same element with the same atomic number but different mass numbers, that is, different numbers of neutrons. Hydrogen has three isotopes: protium (no neutron), deuterium (one neutron) and tritium (two neutrons). Isotopes have the same chemical properties but different masses and, in some cases, different nuclear stability.
Some nuclei are unstable. They change into more stable nuclei by emitting radiation. This spontaneous process is called radioactivity. It was discovered by Becquerel. It is not affected by temperature, pressure or chemical combination. Radioactivity is random: we cannot say when a given nucleus will decay, but a large sample decays in a predictable way. Radiation is detected by a Geiger-Müller counter, a cloud chamber or photographic film.
Three kinds of radiation:
In alpha decay the nucleus loses 2 protons and 2 neutrons, so A falls by 4 and Z by 2: ²³⁸₉₂U → ²³⁴₉₀Th + ⁴₂He. In beta decay a neutron changes to a proton and an electron, so A stays the same and Z rises by 1: ¹⁴₆C → ¹⁴₇N + ⁰₋₁e. In gamma emission the nucleus loses only energy, so A and Z do not change. In every nuclear equation the total mass number and the total charge (atomic number) are the same on both sides.
The half-life T½ of a radioactive nuclide is the time in which half of the nuclei in a sample decay. The activity falls to half in each half-life. After n half-lives the fraction left is (½)ⁿ. Half-lives range from a fraction of a second to billions of years. A short half-life means a rapidly decaying, highly active source. The activity is measured in becquerel (Bq), where 1 Bq = 1 decay per second.
Einstein showed that mass and energy are equivalent: E = Δm c². The energy released is equal to the loss of mass times the square of the speed of light, c = 3 × 10⁸ m/s. A tiny mass converts to a huge energy. Mass defect is the difference between the mass of the separate nucleons and the mass of the nucleus. The energy equivalent of the mass defect is the binding energy that holds the nucleus together. The atomic mass unit is 1 u = 1.66 × 10⁻²⁷ kg, which is equivalent to about 931 MeV.
Nuclear fission is the splitting of a heavy nucleus, such as uranium 235, into two lighter nuclei when it absorbs a slow neutron. A few neutrons and a large amount of energy are released. These neutrons can split more nuclei, producing a chain reaction. In an uncontrolled chain reaction, as in an atomic bomb, the energy is released in an instant. In a nuclear reactor the chain reaction is controlled: control rods of boron or cadmium absorb extra neutrons, and a moderator such as heavy water or graphite slows neutrons. The heat produces steam that turns turbines to generate electricity. Pakistan generates part of its electricity from nuclear power plants, such as those at Karachi and Chashma.
Nuclear fusion is the joining of two light nuclei, for example hydrogen isotopes, to form a heavier nucleus with release of energy. It needs extremely high temperature (millions of degrees) and pressure to overcome the repulsion between positive nuclei. Fusion is the source of energy of the Sun and the stars. It gives more energy per unit mass than fission and produces little long lived waste, but it has not yet been made practical for power plants.
Radioisotopes have many uses. In medicine, cobalt 60 gamma rays treat cancer, and technetium 99m is used for imaging. In industry, radiation checks the thickness of paper and metal sheets and finds leaks in pipes. In agriculture, tracers study how plants take up fertilizer and radiation sterilizes insect pests. Carbon 14 dating finds the age of ancient wood and bones. Gamma rays sterilize surgical tools.
Radiation can ionize atoms in living cells, causing burns, cancer and genetic damage. Safety rules are: keep sources in lead-lined containers, handle them with tongs, limit the time of exposure, stay as far away as possible, use shielding, wear a film badge to record exposure, and dispose of waste safely.
Study tip: For nuclear equations, check the top numbers add up and the bottom numbers add up on both sides. For half-life, first find the number of half-lives n = t / T½ and then halve that many times. Learn the table comparing α, β and γ (nature, charge, ionizing power, penetration, stopping material), as it is often asked.
Say the meaning first, then open the card to check.
A particle in the nucleus, either a proton or a neutron.
Atoms of the same element with the same Z but different mass numbers.
The spontaneous emission of radiation from unstable nuclei.
The time in which half of the radioactive nuclei in a sample decay.
The SI unit of activity, one decay per second.
The difference between the mass of the separate nucleons and the mass of the nucleus.
The splitting of a heavy nucleus into lighter nuclei with the release of energy.
The joining of light nuclei into a heavier nucleus with the release of energy.
A reaction in which neutrons released by one fission cause further fissions.
| Name | Formula | What it means |
|---|---|---|
| Neutron number | N = A − Z | Neutrons equal mass number minus atomic number. |
| Mass energy equivalence | E = Δm c² | Δm in kg, c = 3 × 10⁸ m/s, E in joule. |
| Fraction remaining | N / N₀ = (½)ⁿ | n is the number of half-lives elapsed. |
| Number of half-lives | n = t / T½ | Elapsed time divided by half-life. |
These are the kind of questions asked for 2, 3 and 5 marks. Try each one before opening the answer.
Isotopes are atoms of the same element that have the same number of protons but different numbers of neutrons. Hydrogen, deuterium and tritium are isotopes of hydrogen.
Alpha particles have the greatest ionizing power but the least penetration and are stopped by a sheet of paper. Beta particles ionize less and penetrate more, and are stopped by a few millimetres of aluminium. Gamma rays have the least ionizing power and the greatest penetration, and need thick lead or concrete to reduce them.
The half-life is the time taken for half of the radioactive nuclei in a sample to decay. The activity of the sample also falls to half in this time.
Fission is the splitting of a heavy nucleus such as uranium 235 into two lighter nuclei, with neutrons and energy released. It is used in nuclear reactors and bombs. Fusion is the joining of two light nuclei into a heavier one, with energy released. It needs extremely high temperature and powers the Sun. Fusion gives more energy per unit mass than fission.
When a uranium 235 nucleus splits it releases two or three neutrons, which can split other nuclei and cause a chain reaction. In a reactor, a moderator such as graphite or heavy water slows the neutrons so that they are more likely to cause fission. Control rods made of boron or cadmium absorb extra neutrons. Pushing the rods in lowers the rate of reaction and pulling them out raises it, so exactly one neutron per fission goes on to cause another fission. The heat is used to make steam that drives turbines and generates electricity.
Store the sources in lead-lined containers, handle them with long tongs, limit the time of exposure and keep a large distance from them, and wear protective clothing and a film badge.
Answer: 92 protons, 143 neutrons, 92 electrons
Answer: 5 g
Answer: Thorium 234, A = 234 and Z = 90
Answer: 9 × 10¹³ J
Answer: 150 Bq