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HSSC chemistry

Written by Dr. Ayesha Nadeem (Chemistry)

34 PIEAS Chemistry questions with answers and explanations.

Printable worksheet with answer key

All questions with answers
  1. The atomic number of carbon is:

    • 1 12
    • 2 14
    • 3 6
    • 4 8
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    Correct answer: 6

    Carbon has 6 protons.

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  2. The number of moles in 36 g of water (molar mass 18 g/mol) is:

    • 1 0.5
    • 2 18
    • 3 2
    • 4 4
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    Correct answer: 2

    Moles = mass ÷ molar mass = 36 ÷ 18 = 2.

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  3. The pH of a neutral solution at 25°C is:

    • 1 7
    • 2 0
    • 3 1
    • 4 14
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    Correct answer: 7

    Pure water has equal H⁺ and OH⁻ concentrations at pH 7.

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  4. Avogadro's number is approximately:

    • 1 3.0 × 10⁸
    • 2 6.02 × 10²³
    • 3 6.02 × 10²⁰
    • 4 1.6 × 10⁻¹⁹
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    Correct answer: 6.02 × 10²³

    One mole contains this number of particles.

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  5. The number of valence electrons in a sodium atom (1s² 2s² 2p⁶ 3s¹) is:

    • 1 11
    • 2 8
    • 3 1
    • 4 2
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    Correct answer: 1

    Only the 3s electron is in the outer shell.

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  6. The general formula of the alkanes is:

    • 1 CₙH₂ₙ₊₂
    • 2 CₙH₂ₙ₋₂
    • 3 CₙH₂ₙ
    • 4 CₙHₙ
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    Correct answer: CₙH₂ₙ₊₂

    Alkanes are saturated hydrocarbons, such as CH₄ and C₂H₆.

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  7. The bond in sodium chloride is:

    • 1 Covalent
    • 2 Ionic
    • 3 Hydrogen bond
    • 4 Metallic
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    Correct answer: Ionic

    Sodium transfers an electron to chlorine.

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  8. The oxidation number of manganese in KMnO₄ is:

    • 1 +2
    • 2 +4
    • 3 +7
    • 4 −1
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    Correct answer: +7

    Potassium is +1 and four oxygens are −8, so manganese is +7.

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  9. Boyle's law states that at constant temperature the pressure of a gas is:

    • 1 Inversely proportional to its volume
    • 2 Proportional to its volume
    • 3 Proportional to the square of its volume
    • 4 Independent of its volume
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    Correct answer: Inversely proportional to its volume

    P₁V₁ = P₂V₂ at a fixed temperature.

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  10. A catalyst changes a reaction by:

    • 1 Increasing the yield only
    • 2 Becoming a product
    • 3 Increasing its rate without being used up
    • 4 Lowering the temperature
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    Correct answer: Increasing its rate without being used up

    It gives an easier path for the reaction.

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  11. The hybridisation of carbon in methane is:

    • 1 sp³
    • 2 sp
    • 3 sp³d
    • 4 sp²
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    Correct answer: sp³

    Carbon forms four single bonds in methane.

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  12. The shape of the ammonia molecule is:

    • 1 Trigonal pyramidal
    • 2 Linear
    • 3 Planar triangle
    • 4 Tetrahedral
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    Correct answer: Trigonal pyramidal

    Nitrogen has three bonds and one lone pair.

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  13. In the reaction N₂ + 3H₂ ⇌ 2NH₃, raising the pressure shifts the equilibrium toward:

    • 1 No change
    • 2 Ammonia
    • 3 Nitrogen
    • 4 Hydrogen
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    Correct answer: Ammonia

    There are fewer gas molecules on the right.

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  14. The pH of a 0.01 M solution of hydrochloric acid is:

    • 1 12
    • 2 1
    • 3 2
    • 4 0.01
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    Correct answer: 2

    pH = −log 0.01 = 2.

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  15. Oxidation is the:

    • 1 Gain of neutrons
    • 2 Loss of electrons
    • 3 Gain of electrons
    • 4 Loss of protons
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    Correct answer: Loss of electrons

    Oxidation is loss of electrons.

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  16. In the electrolysis of brine, chlorine gas is formed at the:

    • 1 Container wall
    • 2 Salt bridge
    • 3 Anode
    • 4 Cathode
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    Correct answer: Anode

    Chloride ions are oxidised at the anode.

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  17. The functional group of an alcohol is:

    • 1 −NH₂
    • 2 −COOH
    • 3 −OH
    • 4 −CHO
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    Correct answer: −OH

    Alcohols have a hydroxyl group.

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  18. The IUPAC name of CH₃CH₂OH is:

    • 1 Methanol
    • 2 Ethanol
    • 3 Propanol
    • 4 Ethanal
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    Correct answer: Ethanol

    The two carbon chain gives eth and the OH group gives ol.

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  19. The molarity of a solution made by dissolving 4 g of NaOH (molar mass 40 g/mol) in 500 mL of solution is:

    • 1 0.1 M
    • 2 0.2 M
    • 3 0.8 M
    • 4 2 M
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    Correct answer: 0.2 M

    4 ÷ 40 = 0.1 mol in 0.5 L, which is 0.2 M.

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  20. The number of structural isomers of butane (C₄H₁₀) is:

    • 1 4
    • 2 1
    • 3 3
    • 4 2
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    Correct answer: 2

    They are butane and 2-methylpropane.

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  21. The most electronegative element is:

    • 1 Chlorine
    • 2 Fluorine
    • 3 Oxygen
    • 4 Nitrogen
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    Correct answer: Fluorine

    Fluorine has the highest electronegativity.

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  22. Across a period of the periodic table from left to right, the atomic radius generally:

    • 1 Stays the same
    • 2 Increases
    • 3 Doubles
    • 4 Decreases
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    Correct answer: Decreases

    The nuclear charge rises while the shell stays the same.

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  23. The number of sigma bonds in an ethene molecule (C₂H₄) is:

    • 1 4
    • 2 6
    • 3 2
    • 4 5
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    Correct answer: 5

    There are four C−H bonds and one C−C sigma bond.

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  24. Water has a higher boiling point than hydrogen sulfide because of:

    • 1 Metallic bonding
    • 2 A larger mass
    • 3 Hydrogen bonding
    • 4 Ionic bonding
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    Correct answer: Hydrogen bonding

    Water molecules form hydrogen bonds with each other.

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  25. Avogadro's law says that equal volumes of gases at the same temperature and pressure contain:

    • 1 The same density
    • 2 The same mass
    • 3 The same number of atoms of each element
    • 4 The same number of molecules
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    Correct answer: The same number of molecules

    The number of molecules is the same for every gas.

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  26. For an exothermic reaction the enthalpy change ΔH is:

    • 1 Positive
    • 2 Negative
    • 3 Zero
    • 4 Infinite
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    Correct answer: Negative

    Heat is released, so the enthalpy of the system falls.

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  27. The effect of a catalyst on the value of the equilibrium constant is that it:

    • 1 Doubles it
    • 2 Increases it
    • 3 Decreases it
    • 4 Does not change it
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    Correct answer: Does not change it

    A catalyst speeds up the forward and backward reactions equally, so the constant stays the same.

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  28. The mass of 0.5 mol of calcium carbonate (molar mass 100 g/mol) is:

    • 1 100 g
    • 2 50 g
    • 3 200 g
    • 4 5 g
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    Correct answer: 50 g

    Mass = 0.5 × 100 = 50 g.

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  29. An ionic compound conducts electricity when it is:

    • 1 Solid
    • 2 Cold
    • 3 Molten
    • 4 A powder
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    Correct answer: Molten

    The ions can move only when molten or dissolved.

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  30. The molecular formula of benzene is:

    • 1 C₆H₁₂
    • 2 C₆H₁₄
    • 3 C₅H₆
    • 4 C₆H₆
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    Correct answer: C₆H₆

    Benzene has six carbon atoms and six hydrogen atoms.

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  31. The reaction of methane with chlorine in ultraviolet light is a:

    • 1 Elimination reaction
    • 2 Condensation reaction
    • 3 Substitution reaction
    • 4 Addition reaction
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    Correct answer: Substitution reaction

    A hydrogen atom is replaced by a chlorine atom.

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  32. Which of these is a weak acid?

    • 1 Acetic acid
    • 2 Hydrochloric acid
    • 3 Sulfuric acid
    • 4 Nitric acid
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    Correct answer: Acetic acid

    Acetic acid ionises only slightly in water.

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  33. The percentage of oxygen by mass in water (H = 1, O = 16) is about:

    • 1 88.9%
    • 2 11.1%
    • 3 50%
    • 4 16%
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    Correct answer: 88.9%

    The share is 16 ÷ 18 × 100.

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  34. In an electrochemical cell, reduction takes place at the:

    • 1 Cathode
    • 2 Wire
    • 3 Anode
    • 4 Salt bridge
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    Correct answer: Cathode

    Reduction is gain of electrons at the cathode.

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